A 2.2 W, 80 MHz superscalar RISC microprocessor

A 28 mW/MHz at 80 MHz structured-custom RISC microprocessor design is described. This 32-b implementation of the PowerPC architecture is fabricated in a 3.3 V, 0.5 μm, 4-level metal CMOS technology, resulting in 1.6 million transistors in a 7.4 mm by 11.5 mm chip size. Dual 8-kilobyte instruction and data caches coupled to a high performance 32/64-b system bus and separate execution units (float, integer, loadstore, and system units) result in peak instruction rates of three instructions per clock cycle. Low-power design techniques are used throughout the entire design, including dynamically powered down execution units. Typical power dissipation is kept under 2.2 W at 80 MHz. Three distinct levels of software-programmable, static, low-power operation-for system power management are offered, resulting in standby power dissipation from 2 mW to 350 mW. CPU to bus clock ratios of 1×, 2×, 3×, and 4× are implemented to allow control of system power while maintaining processor performance. As a result, workstation level performance is packed into a low-power, low-cost design ideal for notebooks and desktop computers     

Early childhood socialization in Hispanic families: Context, culture, and practice implications.

Research on early childhood socialization suggests that Hispanic parents differ from parents of other ethnic groups in their child rearing values and the interpersonal behavior they want their children to display at home and school. In this article, the influence of context and culture on child rearing is shown through a review of conceptual frameworks for understanding child socialization in both minority and nonminority families and research on infant–mother attachment and parental beliefs about young children's behavior. This review indicates that parent and child behaviors are a result of different socialization processes that encompass specific cultural values. Implications for professional practice are drawn for child assessment and psychotherapy, family therapy, and parenting skills programs conducted with Hispanics. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Process heat integration of a heavy crude hydrotreatment plant

The present paper focuses on the study of process alternatives for heat integration of a heavy crude oil hydrotreatment plant. Experimental information obtained from a pilot scale, kinetics and reactor modeling tools, and a commercial process simulator were employed to develop mass and energy balances. Four study cases, which employ a combination of quenching and heat exchangers, were identified and evaluated. The results indicated that the case with two quenches with hydrogen and three heat exchangers is the best process heat integration (PHI) option from an energetic point of view.     

Surface chemistry of tribochemical reactions explored in ultrahigh vacuum conditions

The thermal decomposition of model extreme-pressure lubricant additives on clean iron was studied in ultrahigh vacuum conditions using molecular beam strategies. Methylene chloride and chloroform react to deposit a solid film consisting of FeCl₂ and carbon, and evolve only hydrogen into the gas phase. No gas-phase products and less carbon on the surface are detected in the case of carbon tetrachloride. Dimethyl and diethyl disulfide react on clean iron to deposit a saturated sulfur plus carbon layer at low temperatures (∼600 K) and an iron sulfide film onto a Fe + C underlayer at higher temperatures (∼950 K). Methane is the only gas-phase product when dimethyl disulfide reacts with iron. Ethylene and hydrogen are detected when diethyl disulfide is used.     

Downhole Upgrading of Extra-heavy Crude Oil Using Hydrogen Donors and Methane Under Steam Injection Conditions

An extra-heavy crude oil underground upgrading process is described which involves the downhole addition of a hydrogen donor additive under steam injection conditions (280-315°C and residence times of at least 24-h). Laboratory experiments showed a 4° increase in the API gravity (from 9 to 12°) of the upgraded product, a two-fold reduction in the viscosity and, an approximately 8% decrease in the asphaltene content with respect to the original crude. Further increases on the temperature led to products with improved properties reaching 15°API at 315°C. It was found that the presence of the natural formation (catalysts) and methane (natural gas) is necessary to enhance the properties of the upgraded crude oil. From GC and GC-MS results a reaction pathway is proposed that involves hydrogen transfers from tetralin to the extra-heavy crude oil resulting in the formation of 1,2-dihydronaphthalene. This compound is then transformed into naphthalene, further upgrading of crude oil through hydrogen donation. The results of the experiments carried out in the presence and absence of the mineral formation and with an inert solid (SiC) strongly indicate that the former acts as a catalyst and not as a heat transfer matrix. Isotopic labeling studies (CD₄ and ¹³CH₄) give evidences that, most probably, methane is involved in the upgrading reactions.     

A general class of simple majority decision rules based on linguistic opinions

In this paper we have introduced a class of decision rules related to simple majority, by considering individual intensities of preference. These intensities will be shown by means of linguistic labels. In order to compare the amount of opinion obtained by each alternative, we have considered the total ordered monoid generated by the sums of the original labels, according to an addition and an ordering. In this general framework different sets of linguistic labels can be employed and these sets can be represented by means of diverse mathematical objects. Moreover, on these mathematical representations of linguistic labels several orderings can be considered. Thus, flexibility is an important feature of this new class of group decision making procedures. Some examples of putting in practice the simple majority decision rules based on linguistic labels are provided, and the main properties of these voting systems are analyzed. It is worth emphasizing that these properties are satisfied for any total ordered monoid, regardless of the mathematical representation of linguistic labels or the ordering used to compare collective opinions.     

Development of a predictive model for polymer/solvent diffusion coefficient calculations

A new calculation procedure for free‐volume parameters is considered in this work by using viscosity prediction methods and the Levenberg‐Marquardt calculation scheme. All parameters used in the Vrentas–Duda free‐volume theory can be estimated from pure component properties. The prediction results are compared with experimental data for some polymer/solvent systems. The diffusion coefficient calculated by Vrentas–Duda theory can be used in the modeling of membrane separation processes. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Towards a new definition of EPOC parameters for anionic electrochemical catalysts: case of propene combustion

The electrochemical promotion of catalysis (EPOC) of propene combustion was investigated using Pt sputtered thin film on an O²⁻ conductor, 8 mol% Y₂O₃-stabilized-ZrO₂ (YSZ). In order to separate the influence of the thermal migration of the O²⁻ oxide ions from the electrolyte to the catalyst surface and the impact of an electrical polarization on the catalytic activity, several light-off experiments (cool down and heat up procedures) were successively performed under different polarizations, i.e. OCV, +2 and −2 V. These experiments have clearly shown that the presence of O²⁻ (thermally or electrochemically induced) inhibits the catalytic activity of the platinum for the propene deep oxidation. These results demonstrate the importance to define a normalized rate enhancement ratio, ρ _n , from a reference value of the catalytic rate corresponding to a Pt surface state free of O²⁻ ions.